Professor Gon-Ann Lee

Phone

(O) (02)2905-3563

(LAB)(02)29053582

描述: D:\data\eng\Faculty Profiles\teacher\Gon-Ann Lee.jpg

E-mail

016850@mail.fju.edu.tw

Link

 

Experiences and

honors:

B.S., the National Taiwan Normal University  (1980)

M.S., the National Taiwan Normal University (1982)

Ph.D., the Rice University (1990)

 

Postdoctoral Research, the University of Texas, Medical School at Houston (1989-1990)

Associate Professor, Fu-Jen Catholic University (1990-1998) 

Professor, Fu-Jen Catholic University (1998-) 

Chairman, Department of Chemistry, Fu-Jen Cathholic University (1999-2002)(2009-2012)

Field

Organic Chemistry

Research Interests

Dr. Lee's research interests include the synthesis of high strain of small ring compounds (cyclopropenes), calix[4]arenes, and the chemistry of metal-cyclopropenes. A major focus of his research has been the development of a vacuum gas-solid reaction (VGSR) technique for the synthesis of small ring cycloalkenes using reagents adsorbed on inert surfaces to effect elimination reactions. This approach allows the reactive species to be isolated at low temperature, and eliminates many of the undesired bimolecular side reactions that would normally be encountered in solution. Energetic compounds can thus be collected readily in cold traps for further chemical studies or spectral characterization.

Recent Publications

1-      Lee, G.-A.,* Lin, H.-C., Lee, H.-Y., Chen, C.-H., Huang, H.-Y., “Ipso Nitration of 2-Halothiophenes with Silver Nitrate, ” Asian J. Org. Chem. 2017, 6, 1733-1736.

2-      Lee, G.-A.,* Shih, Y.-F., Lin, H.-C., Wang, W.-C., Chan, H.-T., Lee, H.-Y., Lee, C.-Y., “Synthesis of Calix[6]thiophenes and Calix[6]furans, ” ChemistrySelect 2020, 5, 8518-8521.

3-      Lin, H.-C., Tsai, R.-T., Wu, H.-P., Lee, H.-Y., Lee, G.-A.,* “Ene di- and trimerization of 1-methyl-2-cyclopropene, ” Tetrahedron, 2016, 72, 184-191.

4-       Lin, C.-N., Huang, C.-Y., Yu, C.-C., Chen, Y.-M., Ke, W.-M.,Wang, G.-J., Lee, G.-A.,* Shieh, M.-H.,* “Iron carbonyl cluster-incorporated Cu(I) NHC complexes in homocoupling of arylboronic acids: an effective [TeFe3(CO)9]2-ligand, ” Dalton Transactions, 2015, 44, 16675-16679.

5-      Lee, G.-A.,* Lee, H.-Y., Chen, W.-C., Lin, Y.-H., “Reaction of,-unsaturated N-benzenesulfonyl Imine – N – [(2E)-3-phenyl-2-propen-1-ylidene]

benzenesulfonamide with Methyllithium, ” J. Chin. Chem. Soc. 2015, 62, 573-576.

6-           Lee, G.-A.,* Lin, H.-C., “Synthesis of an Anti-Bredt Compound, Bicyclo[3.2.2]nona-1,6,8-triene, via the Isomerization of Tricyclo[3.2.1.02,4]nona-2,6-diene, ” Org. Lett. 2014, 16, 5275−5277.

7-       Lee, G.-A.,* Lee, H.-Y., Wang, W.-C., Cherng, C.-H., “Auto de-bromine-coupling reactions of 1-aryl-7-bromocycloheptenes,” Tetrahedron, 2014, 70, 2956-2961.

8-      Lee, G.-A.,* Chan, L.-E., Tsai, R.-T., Chang, K.-C., “Generation and Chemistry of Tricyclo[3.2.1.02,4]oct-2(3)-ene,” Eur. J. Org. Chem. 2012, 2824–2830.

9-       Lee, G.-A.,* Wang, W.-C., Shieh, M., Kuo, T.-S., “A Novel Synthesis of Calix[4]thiophenes and Calix[4]furans,” Chem. Commun. 2010, 46, 5009–5011.

10-   Lee, G.-A.,* Tsai, R.-T., Wang, W.-C., Liu, Y.-T., “The Synthesis and Trapping of 1-Naphthylcyclopropenes,” J. Chin. Chem. Soc. 2010, 57, 800-804.

11-   Lee, G.-A.,* Wang, W.-C., Jiang, S.-F., Chang, C.-Y., Tsai, R.-T., “The Crossed [2+2] Cycloaddition of 1-Phenylcyclopropene and

Bromo-2-phenylcyclopropene,” J. Org. Chem. 2009, 74, 7994–7997.

12-   Lee, G.-A.,* Chen, K.-C., “The General Synthesis and Trapping of 3-Substituted 1-Chlorocyclopropenes,” Org. Lett. 2008, 9, 1843-1845.

13-    Lo, Y.-L., Wang, W.-C., Lee, G.-A., Liu, Y.-H.,* “Bis(u-l-1H-benzimidazole-5,6-dicarboxylato)bis[tetraaquadicobalt(II)] pentahydrate,” Acta Cryst. 2007, 

E63, m2657-m2658.

14-   Chen, K.-C., Wang, W.-C., Chen, M.-Y., Chen, W.-C., Her, M.-C., Lee, G.-A.,* “Regio- and Stereoselectivity of Ene Reactions: The Dimerization of

Bicyclic 1,3-Fused 2-(TrimethylSilyl)cycloprop-1-enes,” Eur. J. Org. Chem. 2007, 953-958.

15-    陳科州, 李國安,* “環丙烯類化合物的合成與化學性質,” Chemistry (J. Chin. Chem. Soc., Taipei) 2006, 64, 73-96.

16-    Lai, Y.-W., Cherng, J.-J., Sheu, W.-S., Lee, G.-A., Shieh, M.,* “Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with 

Propargyl Bromide,” Organometallics. 2006, 25, 184-190.

17-    Lee, G.-A.,* Chang, C.-Y., “Novel Ene Trimerization of 1-Phenylcyclopropene,” J. Org, Chem. 2004, 69, 8949-8951.

18-    Lee, G.-A.,* Chang, C.-Y., Cherng, C.-H., Chen, C.-S., Liu, M., “The Synthesis and Chemistry of 1,3-Bridged Polycyclic Cyclopropenes:

8-Oxatricyclo[3.2.1.02,4]octa-2,6-dienes,” J. Chin. Chem. Soc. 2004, 51, 839-845.

19-    Lee, G.-A.,* Cherng, C.-H., Huang, A.-N., Lin, Y.-H., “Synthesis and Chemistry of Tricyclic cyclopropene-tricyclo[3.2.2.02,4]nona-2(4),6-diene,” 

Tetrahedron. 2003, 59, 1539-1545.

20-   Lee, G.-A.,* Lin, Y.-H., Huang, A.-N., Li, Y.-C., Chen, C.-S., Jann, Y.-C., Chen, C.-S., “Isomerization of tricyclo[3.2.2.02,4]nona-2(4),6-diene

to the Anti-Bredt Compound 8-Methylenebicyclo[3.2.1]octa-1,6-diene,” J. Am. Chem. Soc. 1999, 121, 5328-5329.

21-   Lee, G.-A.,* Chen, P.-K., Chen, M.-Y., “The Synthesis and Chemistry of 8-Substituted Bicyclo[5.1.0]oct-1(8)-ene ,” J. Chin. Chem. Soc. 1998, 45, 381-385.

22-   Lee, G.-A.,* Chang, C.-Y., “Novel Tetramerization of 1-Trimethylsilyl-2-Phenylcyclopropene,” Tetrahedron Lett. 1998, 39, 3013-3016.

23-   Lee, G.-A.,* Chen, C.-S., “1-Chloro-3-trimethysilylcyclopropene -- A New Synthesis of 3,3'-Bicyclopropyl,” Tetrahedron Lett. 1997, 38, 8717-8720.

24-   Lee, G.-A.,* Huang, A.-N., Chen, C.-S., Li, Y.-C., Jann, Y.-C., “1,2-Bridged Tricyclic Cyclopropenes:Tricyclo[3.2.1.02,4]octa-2(4),6-diene

and Tricyclo[3.2.1.02,4]oct-2(4)-ene,” J. Org. Chem. 1997, 62, 3355-3359.

25-   Chou, S.-S. P., Lee, G.-A.,* “Improvement of Chemistry Courses for Non-Chemistry Major Undergraduates,” J. Chin. Chem. Soc. 1996, 54, 131-143.

26-   Lee, G.-A.,* Chen, J., Chen, C.-S., Shiau, C.-H., Cherng C.-H., “The Synthesis and Chemistry of 9-Chlorobicyclo[6.1.0]non-1(9)-ene,” J. Chin. Chem. Soc. 

1996, 43, 297-300.

27-   Billups, W.-E.,* Luo, W., Lee, G.-A., Chee, J., “Synthesis and chemistry of Bicyclo[4.1.0]hept-1,6-ene ,” J. Org. Chem. 1996, 61, 764-770.

28-    Lee, G.-A.,* Shiau, C.-S., Chen, C.-S., Chen, J., “Regioselectivity of the Ene Reaction: Dimerization of 8-Chlorobicyclo[5.1.0]oct-1(8)-ene,” 

J. Org. Chem. 1995, 60, 3565-3567.

29-   Billups, W.-E.,* Lee, G.-A., Arney, B.-E., Jr., Whitmire, K.-H., “1,3-Bridged Cyclopropenes,” J. Am. Chem. Soc. 1991, 113, 7980-7984.

30-   Billups, W.-E.,* Haley, M.-M., Lee, G.-A., “Bicyclo[n.1.0]alkenes,” Chem. Rev. 1989, 89, 1147-1159.

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