劉彥祥 學術特聘教授

通訊處

辦公室電話︰(02)2905-3570

實驗室電話：(02)2905-2482

E-mail

chem2022@mails.fju.edu.tw

學經歷

東吳大學化學系學士(1987)

美國Louisiana State University, Baton Rouge博士(1997)

田其芳股份有限公司光阻事業部總經理特助

中央研究院化學所博士後研究員

東吳大學化學系兼任助理教授

淡江大學化學系兼任助理教授

輔仁大學化學系助理教授

輔仁大學化學系副教授

輔仁大學化學系教授
輔仁大學化學系學術特聘教授

輔仁大學化學系系主任(2018.8~2020.7)

獲獎紀錄

97學年度 理工學院教師及研究人員研究成果獎勵

98學年度 理工學院教師及研究人員研究成果獎勵

99學年度 理工學院教師及研究人員研究成果獎勵

100學年度 國家科學委員會特殊優秀人才獎勵

101學年度 國家科學委員會特殊優秀人才獎勵

102學年度 國家科學委員會特殊優秀人才獎勵

102學年度 國家科學委員會特殊優秀人才獎勵

103學年度 國家科學委員會特殊優秀人才獎勵

104學年度 國家科學委員會特殊優秀人才獎勵

105學年度 國家科學委員會特殊優秀人才獎勵

106學年度 國家科學委員會特殊優秀人才獎勵

學術專長

無機化學

研究領域

研究領域

本實驗室主要研究領域包含無機配位化學、固態化學以及超分子化學。研究範圍包含以下主題：

1, 單晶X-ray繞射結構解析

2. 晶體工程

3. 有機–無機混成多孔性吸附材料

4, 功能性固態光、電、磁自組裝配位聚合物

 

有機–無機混成配位聚合物之設計與合成：

設計與合成具有特殊幾何形狀與配位基之有機配子，與過渡金屬或鑭系金屬鹽類離子在受控制的水熱條件或室溫中進行超分子自組裝反應。藉有機配子的幾何形狀及金屬簇配位幾何結合，形成具特殊架構之固態結晶性配位聚合物(Scheme 1)。以單晶X-光繞射法進行晶體結構分析。並進而研究其因結構之多維架構特質導引之物理及化學性質。例如多孔性吸附、特殊之放光、離子導電、或磁性等性質的研究。

 

Scheme 1. 超分子自組裝配位聚合物之設計概念.

Metal-Ligand Coordination:

描述: 描述: 描述: Untitled

研究室成果：

描述: 描述: 描述: YHLiuWebpage

代表著作

1.     Thanasekaran, P.;  Su, C. H.;  Liu, Y. H.; Lu, K. L., Hydrophobic Metal–Organic Frameworks and Derived Composites for Microelectronics Applications. Chemistry – A European Journal 2021, 27, 16543–16563.

2.     Thanasekaran, P.;  Su, C. H.;  Liu, Y. H.; Lu, K. L., Weak Interactions in Conducting Metal–Organic Frameworks. Coordination Chemistry Reviews 2021, 442, 213987.

3.     Ngue, C. M.;  Liu, Y. H.;  Leung, M.; Lu, K. L., Reversible Electroactive Behavior in a Zn-Based Metal–Organic Framework via Mild Oxidation Potential. Inorganic Chemistry 2021, 60, 11458–11465.

4.     Hsu, K. T.;  Thanasekaran, P.;  Hsu, T. W.;  Su, C. H.;  Chang, B. C.;  Liu, Y. H.;  Hung, C. H.; Lu, K. L., A Nonlinear Optical Cadmium(II)-Based Metal–Organic Framework with Chiral Helical Chains Derived from an Achiral Bent Dicarboxylate Ligand. CrystEngComm 2021, 23, 824–830.

5.     Wu, H. W.;  Lee, L. W.;  Thanasekaran, P.;  Su, C. H.;  Liu, Y. H.;  Chin, T. M.; Lu, K. L., Weak Interactions in Imidazole-Containing Zinc(II)-Based Metal–Organic Frameworks. Journal of the Chinese Chemical Society 2020, 67, 2182–2188.

6.     Inamdar, A. I.;  Pathak, A.;  Usman, M.;  Chiou, K. R.;  Tsai, P. H.;  Mendiratta, S.;  Kamal, S.;  Liu, Y. H.;  Chen, J. W.;  Chiang, M. H.; Lu, K. L., Highly Hydrophobic Metal–Organic Framework for Self-Protecting Gate Dielectrics. Journal of Materials Chemistry A 2020, 8, 11958–11965.

7.     Usman, M.;  Feng, P. H.;  Chiou, K. R.;  Chen, J. W.;  Lee, L. W.;  Liu, Y. H.; Lu, K. L., Polar Molecule Confinement Effects on Dielectric Modulations of Sr-Based Metal–Organic Frameworks. ACS Applied Electronic Materials 2019, 1, 836–844.

8.     Ngue, C. M.;  Liu, Y. H.;  Wen, Y. S.;  Leung, M. K.;  Chiu, C. W.; Lu, K. L., Spectroelectrochemical Studies of the Redox Active Tris[4-(triazol-1-yl)phenyl]amine Linker and Redox State Manipulation of Mn(II)/Cu(II) Coordination Frameworks. Dalton Transactions 2019, 48, 10122–10128.

9.     Lee, L. W.;  Kao, Y. C.;  Chung, M. Y.;  Chang, B. C.;  Lee, G. H.;  Peng, S. M.;  Wang, C. M.;  Liu, Y. H.;  Lee, S. L.; Lu, K. L., Rare Metal-ion Metathesis of a Tetrahedral Zn(II) Core of a Noncentrosymmetric (3,4)-Connected 3D MOF. Dalton Transactions 2019, 48, 1950–1954.

10.   Ngue, C. M.;  Chiu, C. W.;  Lee, G. H.;  Peng, S. M.;  Leung, M. K.;  Yang, C. I.;  Liu, Y. H.; Lu, K. L., A Co(II) Framework Derived from a Tris(4-(triazol-1-yl) phenyl) Amine Redox-Active Linker: An Electrochemical and Magnetic Study. Dalton Transactions 2018, 47, 9341–9346.

11.   Lee, L. W.;  Luo, T. T.;  Lo, S. H.;  Lee, G. H.;  Peng, S. M.;  Liu, Y. H.;  Lee, S. L.; Lu, K. L., Pillared-Bilayer Zinc(II)–Organic Laminae: Pore Modification and Selective Gas Adsorption. CrystEngComm 2015, 17, 6320–6327.

12.   Peng, Y. R.;  Chien, P. H.;  Chung, H. T.;  Pan, P. Y.;  Liu, Y. H.; Yang, E. C., Studies of the Structural and Magnetic Properties of an Unsymmetrical Ligand 1,2,4-Benzenetricarboxylic acid Based Chiral 3-D Trinickel Coordination Polymer as an Alkali Base-Influenced Hydrothermal Reaction Product. Journal of Solid State Chemistry 2014, 212, 159–164.

13.   Liu, Y. H.; Chien, P. H., A Series of Lanthanide–Organic Frameworks Possessing Arrays of 2D Intersecting Channels within a 3D Pillar-Supported Packed Double-Decker Network and Co2+-Induced Luminescence Modulation. CrystEngComm 2014, 16, 8852–8862.

14.   Liu, Y. H.;  Peng, C. C.;  Lee, S. H.;  Chien, P. H.; Wu, P. C., In situ Resolved Ligand Chirality in Preparing a Chiral 3D Zinc-Cyclopentane-Tetracarboxylate Based Coordination Polymer. CrystEngComm 2013, 15, 10333–10339.

15.   Liu, Y. H.;  Lee, S. H.;  Chiang, J. C.;  Chen, P. C.;  Chien, P. H.; Yang, C. I., Dehydration Induced 2D-to-3D Crystal-to-Crystal Network Re-assembly and Ferromagnetism Tuning within Two Chiral Copper(II)-Tartrate Coordination Polymers. Dalton Transactions 2013, 42, 16857–16867.

16.   Lee, C. H.;  Huang, H. Y.;  Liu, Y. H.;  Luo, T. T.;  Lee, G. H.;  Peng, S. M.;  Jiang, J. C.;  Chao, I.; Lu, K. L., Cooperative Effect of Unsheltered Amide Groups on CO2 Adsorption Inside Open-Ended Channels of a Zinc(II)–Organic Framework. Inorganic Chemistry 2013, 52, 3962–3968.

17.   Chung, H. T.;  Yang, C. I.;  Yang, E. C.;  Peng, C. C.;  Tsai, H. L.; Liu, Y. H., Metamagnetic Behavior and Moisture-Absorption Induced Reversible Network Assembly of a Cobalt-1,2,4-Benzenetricarboxylate Supramolecular Network. CrystEngComm 2012, 14, 1317–1323.

18.   Chang, C. C.;  Huang, Y. C.;  Huang, S. M.;  Wu, J. Y.;  Liu, Y. H.; Lu, K. L., Presynthesized and In-Situ Generated Tetrazolate Ligand in the Design of Chiral Cadmium Coordination Polymer. Crystal Growth & Design 2012, 12, 3825–3828.

19.   Yang, C. I.;  Song, Y. T.;  Yeh, Y. J.;  Liu, Y. H.;  Tseng, T. W.; Lu, K. L., A Flexible Tris-Phosphonate for the Design of Copper and Cobalt Coordination Polymers: Unusual Cage Array Topology and Magnetic Properties. CrystEngComm 2011, 13, 2678–2686.

20.   Liu, Y. H.;  Fang, H. P.;  Jhang, P. C.;  Peng, C. C.;  Chien, P. H.;  Yang, H. C.;  Huang, Y. C.; Lo, Y. L., A New Cd-4-2,4-Pyridinedicarboxylate Layered Coordination Polymer Consisting of Intralayer Cavities and Reversible Network Self-Adaptation upon Dehydration/Moisture-Absorption. CrystEngComm 2010, 12, 1779–1783.

21.   Wu, J. Y.;  Ding, M. T.;  Wen, Y. S.;  Liu, Y. H.; Lu, K. L., Alkali Metal Cation (K+, Cs+) Induced Dissolution/Reorganization of Porous Metal Carboxylate Coordination Networks in Water. Chemistry – A European Journal 2009, 15, 3604–3614.

22.   Lin, Y. C.;  Chen, W. T.;  Tai, J.;  Su, D.;  Huang, S. Y.;  Lin, I.;  Lin, J. L.;  Lee, M. M.;  Chiou, M. F.;  Liu, Y. H.;  Kwan, K. S.;  Chen, Y. J.; Chen, H. Y., Tuning Through-Bond Fe(III)/Fe(II) Coupling by Solvent Manipulation of a Central Ruthenium Redox Couple. Inorganic Chemistry 2009, 48, 1857–1870.

23.   Ding, M. T.;  Wu, J. Y.;  Liu, Y. H.; Lu, K. L., Dissolution/Reorganization toward the Destruction/Construction of Porous Cobalt(II)- and Nickel(II)-Carboxylate Coordination Polymers. Inorganic Chemistry 2009, 48, 7457–7465.

24.   Chung, H. T.;  Tsai, H. L.;  Yang, E. C.;  Chien, P. H.;  Peng, C. C.;  Huang, Y. C.; Liu, Y. H., A New Manganese Coordination Polymer Containing 1,2,4-Benzenetricarboxylic Acid. Chemistry – A European Journal 2009,  3661–3666.

25.   Wu, J. Y.;  Yang, S. L.;  Luo, T. T.;  Liu, Y. H.;  Cheng, Y. W.;  Chen, Y. F.;  Wen, Y. S.;  Lin, L. G.; Lu, K. L., Time-Evolving Self-Organization and Autonomous Structural Adaptation of Cobalt(II)-Organic Framework Materials with scu and pts Nets. Chemistry – A European Journal 2008, 14, 7136–7139.

26.   Tsai, C. J.; Liu, Y. H., Poly[diaquabis(2,2 '-bipyridine)tris(mu(4-)2,2 '-bipyridine-4,4 '-dicarboxylato)-dineodymium(III)]. Acta Crystallographica Section E-Crystallographic Communications 2008, 64, M260-U2441.

27.   Luo, T. T.;  Liu, Y. H.;  Chan, C. C.;  Huang, S. M.;  Chang, B. C.;  Lu, Y. L.;  Lee, G. H.;  Peng, S. M.;  Wang, J. C.; Lu, K. L., Toward Quartz and Cristobalite: Spontaneous Resolution, Structures, and Characterization of Chiral Silica-Mimetic Silver(I)–Organic Materials. Inorganic Chemistry 2007, 46, 10044–10046.

28.   Liu, Y. H.; Jhang, P. C., Catena-Poly[[[diaquanickel(II)]-mu-pyridine-2,4-dicarboxylato-[tetraaquanickel(II)]-mu-pyridine-2,4-dicarboxylato] dihydrate]. Acta Crystallographica Section E-Crystallographic Communications 2007, 63, M1682-U961.

29.   Liu, Y. H.; Ding, M. T., Poly[[tetraaqua(mu(6)-benzene-1,2,4,5-tetracarboxylato)dicobalt(II)] dihydrate]. Acta Crystallographica Section E-Crystallographic Communications 2007, 63, M1828-U554.